Phys Chem
wise 23
wise 23
Set of flashcards Details
| Flashcards | 33 |
|---|---|
| Language | Deutsch |
| Category | English |
| Level | Secondary School |
| Created / Updated | 26.12.2017 / 06.01.2023 |
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(dH/dp)S
V
dG in Abh. von Q
dG = dRG0 + RT lnQ
dRG0 im GGW
-RT* ln(K)
d ln(Kp) / dT
dRH0 / RT2 Van't Hoff Gleichung
Van't Hoff Gleichung
d ln(Kp) / dT = dRH0 / RT2
dRG in Abh von dRH0
dRG = dRH0 -T dRS0
Clapeyron'sche Gleichung
(dp/dT) Coex = (dS/dV) a--->b (Phase a zu Phase b) = (dHmol / T dVmol )
Clausius Clapeyron'sche Gleichung
(dp/dT) Coex = p dHmol / RT2
Faraday Gesetz dRG ?
dRG = -z F E
Nernst Gleichung
E = E0 -RT/zF ln Q, ln (Red/Ox)
dE0/dT
dRS0/ zF
dRH0 in Abh von E0
dRH = -zF (E0-T dE0/dT)
Schwingungsfreihetisgrade für nicht lineare und lineare Moleküle und Rot. f
nicht linear : 3N -5
linear : 3N -6
rotationsfreiheitsgrade nicht linear : 3
linear : 2
translation immer 3
U in abh von f (fReiheitsgrade)
U = f/2 nRT
cp in Abh von cv
cp - cv = R
dU
dU = TdS - pdV
dH
dH = TdS + VdP
dA
-SdT - pdV
dG
dG = -SdT + VdP
H
H = U + pV
A
A = U - TS
G in Abh von H
G = H - TS
G in Abh von U
G = U + pV - TS
(dA/dT)v
-S
(dA/dV)T
-p
(dG/dT)p
-S
(dG/dp)T
V
(dS/dT)p
Cp/T
-(dS/dV)T
d/dV (dA/dT)V = -(dp/dT)V
-(dp/dT)V
-(dS/dV)T
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