Wood Physics & Wood Materials

ETHZ / D-BAUG / FS23

ETHZ / D-BAUG / FS23


D. B.
This flashcard set delves into the intricate world of wood physics and materials, catering to university-level students. It explores the structure and properties of wood, focusing on cells, density, moisture, and various types of wood materials. The flashcards cover topics like water transport, swelling, and shrinkage anisotropy, as well as the production of cellulose nanofibers. They also differentiate between angiosperms and gymnosperms, evergreen and deciduous trees, and discuss the importance of density in wood. This set is particularly beneficial for students studying forestry, materials science, or related fields, providing them with a comprehensive understanding of wood's physical properties and applications.
Flashcards
102
Students
1
Language
English
Category
Nature Studies
Level
University
Created / Updated
17.07.2023 / 10.08.2023

Flashcards

Optical properties

wood color changes due to aging

  • light exposure (UV light)
  • heat and oxygen exposure

most wood species get darker

some get yellower (maple, birch)

some get lighter (teak, thermowood)

UV protection

Application of coating systems with:

  • organic UV absorbers and organic radical scavengers
  • metal oxides (nanoparticle-based systems)

new systems:

  • growth of nanorods on wood surfaces

 

Fire triangle

Flashing point, Auto-ignition and Pyrolysis

Flashing Point: The temperature at which wood when exposed to a flame starts to burn due to thermal decomposition
--> above 225°C for wood of medium density

Auto-ignition: Temperature at which wood spontaniously ignites in a normal atmosphere without an external source of ignition
--> above 280°C

Pyrolysis: Decomposition of wood with formation of char and flammable gases.

Burning rate

Depth of char layer as a function of fire duration. Helps to estimate how long a certain piece of wood could hold a certain weight while burning.

\(\beta (t) = \frac{d_{char}}{t}\)   for example spruce ≈ 0.7 [mm/min]

depends on:

  • exposure to fire
  • pressure
  • temperature
  • wood species

Brandverhaltensgruppen

In Switzerland, building materials are classified according to their reaction to fire:

RF1 = no contribution to fire

RF2 = little contribution to fire

RF3 = admissible contribution to fire

RF4 = inadmissible contribution to fire

Wood fire behavior - EN

Building material class B

 

Influence of wood density:

  • Density < 300 kg/m^3         high flammability
  • Density 300-1000 kg/m^3   moderate flammability
  • Density > 1000 kg/m^3       low flammability

(relates to air accessibility in wood!)

Intumescent coating systems

They offer passive fire protection by swelling in response to high temperatures, increasing in volume and decreasing in density. --> creates an insulating barrier layer

Intumescent materials:

  • Binding agent
    • polymers like polyamides, polyuretane acrylates
  • Blowing agent
    • urea, melamine, polyamides
  • Inorganic acid source
    • ammonium salts, phosphates, sulfates
  • Polyhydric compounds (carbon source)
    • starch, pentaerythirol, char former polymers

Cone calorimetry

Measures a material's flammability using the technique of oxygen consumption calorimetry (OCC).

Determines the HRR of a fire by measuring the amount of oxygen the fire consumes.

Wood-mineral hybrids with improved fire resistance

  • surface coatings
  • bulk treatments
  • bulk mineralization (CaCO3)
    • via decomposition of dimethyl carbonate (DMC)
    • or via mineralisation by alternating salt solutions

 

Fire resistance of wood

Intrinsic wood factors:

  • wood species
  • density (higher density --> higher resistance)
  • thickness of element

treatments:

  • surface coatings and treatments (e.g. intumescent)
  • bulk treatments and impregnation (e.g. mineralization)

important parameters:

  • Heat release rate
  • Burning rate
  • Smoke release rate

Wood - mechanical summary

Wood is a inhomogeneous, anisotropic and porous solid, whose properties are affected mainly by its structure, moisture and temperature.

Transparent wood for solar cells

Transparent wood layer for:

  • mechanical properties
  • insulation (low thermal conductivity)
  • light scattering (haze)
  • sustainability

Conductivity of different materials

Conductor, Insulator and Dielectric

Conductor

A material that allows the flow of electric charge. It conducts electric current very efficiently due to the presence of free electrons that can move easily throughout the material.

Insulator

A material that resists the flow of electric charge. It has few free electrons, so it does not allow electric current to pass through it easily.

Dielectric

A type of insulator that can be polarized when an electric field is applied. This property makes dielectrics useful in various applications, such as in capacitors where they can store energy in an electric field.

Graphitization of wood

To increase its eletric conductivity

via:

  • bulk graphitization (by impregnation)
  • laser-induced graphitization

Piezoelectricity of wood

Piezoelectricity is the property of certain materials to generate an electric charge in response to applied mechanical stress.

in wood:

  • compression in one direction increases the polarization (or charge seperation) between O and the electropositive Si atoms
     
  • when a positive potential is applied to the surface, Si atoms are forced away, producing a mechanical deformation (reverse piezoelectric effect)

Triboelectricity of wood

The triboelectric effect refers to the electric charge that is generated when two different materials come into contact and are then separated.

Thermal conductivity in wood

Thermal conductivity of wood (with a moisture content of 12%) perpendicular and parallel to fibre grain:

\(\lambda_{\perp} = 0.026 + 0.195 \cdot \rho \cdot 10^{-3} \quad [W/mk] \)

\(\lambda_{\parallel} = 0.026 + 0.46 \cdot \rho \cdot 10^{-3} \quad [W/mk] \)

is a function of bulk density!

And increases linearly with moisture content

Specific heat capacity

Heat quantity that is needed to increase the temperature of 1 kg of a material by 1 K.

oven-dry wood --  \(\approx 1300 \left[ \frac{J}{kg \cdot K}\right]\)

  • minor density influence
  • distinct humidity influence

water -- \(4181 \left[ \frac{J}{kg \cdot K}\right]\)

Thermal diffusivity

Thermal diffusivity is the rate at which heat spreads ("diffuses") through a material, from its hot end to its cold end.

\(a = \frac{\lambda}{c \cdot \rho} \cdot 10^{-3} \left[ \frac{m^2}{s} \right]\)

\(c \quad \text{Specific heat capacity in} \left[ \frac{kJ}{kg \cdot K} \right]\)

\(\rho \quad \text{Bulk density in} \left[ \frac{kg}{m^3} \right]\)

\(\lambda \quad \text{Thermal conductivity in} \left[ \frac{W}{m \cdot K} \right]\)

decreases with increasing moisture content

Washboard effect

Due to different thermal expansion of plywood layers.

Heartwood and Sapwood

Heartwood (Kernholz)

Heartwood, also called duramen, is dead, central wood of trees. Its cells usually contain tannins or other substances that make it dark in color and sometimes aromatic. Heartwood is mechanically strong, resistant to decay, and less easily penetrated by wood-preservative chemicals than other types of wood. One or more layers of living and functional sapwood cells are periodically converted to heartwood.

 

Sapwood (Splintholz)

You can typically identify the sapwood in a tree as it is lighter in color. This is new wood and is used to move water throughout the tree up to the leaves. Excess nutrients are often stored here as well. All wood in a tree is first formed as sapwood.

Phloem and Xylem

Phloem and xylem are two types of transport tissue in vascular plants, and they serve different functions.

Phloem

The main function of phloem is to transport organic nutrients, especially sucrose, a sugar produced by photosynthesis in the leaves, to all parts of the plant where needed. This process is known as translocation.

Phloem tissue is composed of several different kinds of cells, including sieve tube elements and companion cells. Unlike xylem, the cells in phloem are alive at maturity.

Xylem

The primary function of xylem is to transport water and dissolved minerals from the roots to the rest of the plant, including the stems and leaves.

Xylem tissue is composed of elongated cells that are usually dead and empty of cell contents at maturity. This structure allows them to act like tiny tubes for transporting water and nutrients. The walls of xylem cells are thickened with lignin, a compound that gives the cells strength and prevents them from collapsing.

In trees, the bulk of the wood is made up of xylem tissue, which also provides structural support.

Sap

Sap is a fluid transported in xylem cells (vessel elements or tracheids) or phloem sieve tube elements of a plant. These cells transport water and nutrients throughout the plant.

Saps may be broadly divided into two types:

  • phloem sap
    • watery solution of hormones, minerals and other nutrients
    • movement from roots towards the leaves
  • xylem sap
    • watery solution of sugars, hormones and minerals
    • movement from leaves to where sugars are used or stored (sugar sinks)

Cambium

Cambium is a thin layer of plant tissue inbetween the xylem and phloem.

Its primary role is to facilitate plant growth. It produces new phloem towards the outside and new xylem to the inside.

Tracheid

A tracheid is a long and tapered lignified cell in the xylem of vascular plants.

The main functions of tracheid cells are to transport water and inorganic salts, and to provide structural support for trees.

Tracheids are dead at functional maturity and do not have a protoplast.

Transpiration

Transpiration is the process of water movement through a plant and its evaporation from aerial parts, such as leaves, stems and flowers.

Transpiration occurs through the stomatal apertures, and can be thought of as a necessary "cost" associated with the opening of the stomata to allow the diffusion of carbon dioxide gas from the air for photosynthesis. Transpiration also cools plants, changes osmotic pressure of cells, and enables mass flow of mineral nutrients and water from roots to shoots.

The rate of transpiration is regulated by the plant's stomata, tiny pores on the leaf surface that open and close to allow the exchange of gases and water vapor between the plant and the atmosphere.

Mass flow of liquid water from the roots to the leaves is driven in part by capillary action, but primarily driven by water potential differences.

Cohesion-tension theory

The cohesion-tension theory explains how leaves pull water through the xylem. Water molecules stick together or exhibit cohesion. As a water molecule evaporates from the surface of the leaf, it pulls on the adjacent water molecule, creating a continuous flow of water through the plant.

Primary and secondary growth

In botany, secondary growth (cambial growth) is the growth that results from cell division in the cambia or lateral meristems and that causes the stems and roots to thicken, while primary growth is growth that occurs as a result of cell division at the tips of stems and roots, causing them to elongate, and gives rise to primary tissue.

Cell wall

Wood cells, also known as tracheids or fibers, have a primary and secondary cell wall.

The primary cell wall is thin and flexible, and it expands as the cell grows. It's mainly composed of cellulose, hemicellulose, pectin, and proteins.

The secondary cell wall forms after the cell has completed its growth and is considerably thicker than the primary wall. It provides rigidity and strength to the cell and is primarily responsible for the mechanical properties of the wood. It's primarily composed of cellulose, hemicellulose, and lignin.

 

Cellulose

Composed of long chains of glucose molecules. These chains bundle together to form microfibrils. Cellulose microfibrils provide the main structural support in the cell wall.

Hemicellulose

Made up of various different sugar monomers. Acts like a filler between cellulose microfibrils, helping to bind them together.

Pectin

Complex polysaccharides rich in galacturonic acid. Pectin is the principal component of the middle lamella and is responsible for the jelly-like matrix in which the cellulose and hemicellulose are embedded.

Lignin

A complex, highly branched polymer often associated with the secondary cell walls of woody plants. Being rather hydrophobic, it waterproofs the cell walls of the water-conducting cells in xylem, which helps plants transport water more efficiently.

Proteins

There are many different proteins in the cell wall with a variety of functions. Some are structural proteins that contribute to the strength and elasticity of the cell wall, while others play roles in cell growth and expansion, defense against pathogens, or communication between cells.

Cell types

Parenchyma Cells: These cells have thin and flexible primary cell walls. They are involved in metabolic functions, storage, and tissue regeneration.

Collenchyma Cells: These cells have thickened primary cell walls that provide support for the plant, particularly in regions of active growth.

Sclerenchyma Cells: These cells have thick secondary cell walls often reinforced with lignin, a complex organic polymer that provides rigidity. These cells provide the main structural support to the plant.

Xylem Cells: Tracheids and vessel elements, the main types of xylem cells, have thick secondary cell walls fortified with lignin. These cells, dead at maturity, form hollow tubes for water and nutrient transport.

Phloem Cells: The cell walls of sieve-tube elements in the phloem have sieve plates (areas with many small holes) that allow for the transport of sugars and other organic compounds.

Epidermal Cells: These cells form a protective layer on the plant surface and have a variety of cell wall adaptations, such as a waxy cuticle layer that prevents water loss

Wood and wood-based products

Wood-based products

Made of raw wood or solid wood by processing it to structures, particles, or fibers and subsequent assembly.

  • glued laminated timber
  • veneer laminates
  • particleboards
  • fibreboards
  • composite panels

Solid wood

Made of raw wood by longitudinal or cross-sectional cut.

  • round timber
  • sawn timber
  • veneer

Wood-based products

solid-wood products

  • solid wood boards
  • glued laminated timber
  • cross-laminated timber

veneer-based products

  • laminated veneer lumber (LVL)
  • plywood
  • parallel strand lumber (Parallam)

particle-based products

  • particle board
  • oriented strand board (OSB)
  • laminated strand lumber LSL (extremely long chips compared to OSB)
  • waferboard (weaker and less-stiff cousin of OSB, larger chips)

fibre-based products

  • medium density fiberboard (MDF)
  • porous fibreboard
  • hard fiberboard

composite materials

  • composite boards
  • wood flooring panels

Solid wood and veneer-based products

veneer-based products

  • veneer production by rotary cut
  • control of the properties via the fiber direction in the layers
  • Parallam --> gluing and compression to beam elements
     
  • ski and snowboard cores

Wood utilization of wood-based products

sawn timber (40 - 50 %)

plywood (50 - 60 %)

OSB (80 - 85 %)

LSL (80 - 85 %)

MDF (87 - 90 %)

particle board (88 - 93 %)

Distinctions of fiber-based products

bulk density

  • soft
  • medium
  • hard
  • extra hard

cross-section structure

  • single-layered
  • multi-layered
  • continuous

adhesive

  • urea resin
  • phenolic resin
  • bitumen
  • lignin

surface

  • sanded
  • coated

resistance

  • moisture protected
  • fungi-protected
  • fire-resistant

formaldehyde emission

  • very low
  • low
  • medium
  • high

Distinctions of particle-based products

particle type/orientation

  • top layer particles
  • middle layer particles
  • wafers
  • flakes

cross-section structure

  • single-shift
  • three-layered
  • multilayered
  • continuous
  • homogeneous cross section structure

bulk density

  • low
  • medium
  • high

adhesive/binder

  • urea resin
  • phenolic resin
  • melamine resin
  • isocyanates
  • cement
  • gypsum
  • tannins

formaldehyde emission

  • very low
  • low
  • medium
  • high

production process

  • different press processes

surface

  • sanded
  • coated

resistance

  • moisture-protected
  • fungi-protected
  • fire-resistant

Swelling of particle boards

swelling increases with density

thickness swelling of particle boards is significantly higher than that of solid wood
(spring back effect)

thickness swelling of wood-based products is largely irreversible
swelling of solid wood is reversible

Wood-based composite products

middle layer:

  • solid wood
  • with cavities
  • particle boards
  • foams

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